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Class 11 Chemistry Chapter 1: Some Basic Concepts of Chemistry MCQs with answers

10 multiple-choice questions on Some Basic Concepts of Chemistry, each with its answer and the reason, written from the NCERT chapter. For school exams on the CBSE pattern, JEE Main and NEET, which are set from the same NCERT chapter. Open a question's solution to check your working; then take the free test to find your next chapter.

Question 1
An aqueous solution is warmed from 20 °C to 40 °C, with no loss of solvent. Which way of stating its concentration changes?
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Answer: (d) molarity

Molarity is moles per litre of solution, and the volume of a solution changes with temperature. Molality, mass per cent and mole fraction depend only on masses or moles, which do not change on warming.

Question 2
Which of the following is a homogeneous mixture?
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Answer: (b) air

Air is a mixture whose components are uniformly distributed, so its composition is the same throughout. Salt with sugar, and grains with dirt, are heterogeneous; glucose is a pure substance (a compound).

Question 3
Which of these facts about a strip of magnesium ribbon can be found only by making a chemical change happen?
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Answer: (c) whether it burns in air to form magnesium oxide

Combustibility is a chemical property: observing it needs the magnesium to change into a new substance, magnesium oxide. Colour, density and melting point are physical properties, measured without changing the identity of the metal.

Question 4
The bond length in a molecule is 0.45 nm. Expressed in picometres it is
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Answer: (a) 450 pm

1 nm = 10⁻⁹ m and 1 pm = 10⁻¹² m, so 0.45 nm × (10⁻⁹ m / 1 nm) × (1 pm / 10⁻¹² m) = 0.45 × 10³ pm = 450 pm.

Question 5
Liquid nitrogen boils at −196 °C. On the Kelvin scale this temperature is
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Answer: (a) 77.15 K

K = °C + 273.15 = −196 + 273.15 = 77.15 K. A negative value is not possible on the Kelvin scale; 469.15 comes from subtracting instead of adding.

Question 6
At what temperature do a Celsius thermometer and a Fahrenheit thermometer show the same number?
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Answer: (c) −40°

Put °F = °C = x in °F = (9/5)(°C) + 32: x = 9x/5 + 32, so −4x/5 = 32 and x = −40. So −40 °C = −40 °F.

Question 7
Which of these measurements has the same number of significant figures as 0.02060 g?
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Answer: (b) 20.60 g

In 0.02060 the leading zeros are not significant, the zero between 2 and 6 is, and the terminal zero after the decimal point is: four figures (2, 0, 6, 0). 20.60 also has four. 2060 (no decimal point) has three, and 2.06 and 0.206 have three.

Question 8
A student weighs three portions of a salt on different balances, 4.2 g, 0.153 g and 12.07 g, and mixes them. The total mass correctly reported is
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Answer: (d) 16.4 g

The sum is 16.423 g. In addition the result may carry no more decimal places than the least precise figure, 4.2 g (one decimal place), so it is reported as 16.4 g.

Question 9
A metal piece of mass 12.5 g raises the water level in a measuring cylinder by 4.6 mL. Its density, reported to the correct number of significant figures, is
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Answer: (c) 2.7 g mL⁻¹

Density = mass/volume = 12.5 g / 4.6 mL = 2.717... g mL⁻¹. In division the result keeps the significant figures of the least precise measurement: 4.6 has two, so the density is 2.7 g mL⁻¹.

Question 10
Using the rule for a dropped digit of exactly 5, which pair of numbers is correctly rounded to two decimal places?
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Answer: (a) 4.725 → 4.72 and 3.635 → 3.64

When the digit removed is 5, the preceding digit is left unchanged if it is even and raised by one if it is odd. In 4.725 the preceding digit 2 is even, giving 4.72; in 3.635 the preceding digit 3 is odd, giving 3.64.

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